Collection of Czechoslovak Chemical Communications · 1981 · 19 citations · 0 references
Natural SciencesChemical EngineeringChemistryCatalysisChemical KineticsPhysical ChemistryCatalytic MaterialsCatalytic Reaction KineticsChemical Kinetics ModelingChemical Reaction KineticsKinetic ModelingSupported CatalystsAtmospheric PressureAtmospheric Pressure DependenceCatalyst ActivityCatalyst KineticsCatalytic Reaction MechanismsCatalytic Surface KineticsKinetic MeasurementPalladium Catalysts
Kinetics of hydrogenation of 1,3- and 1,5-cyclooctadiene and cyclooctene on palladium support catalysts (Pd/CaCO 3 , Pd/γ-Al 2 O 3 ) were measured in heptane solutions at 300 K and atmospheric pressure of hydrogen. The kinetic constants were obtained by relating the experimental data to a kinetic model in which the partial reactions are assumed to be 1 st order.