Concepedia

Synthesis and Structure of (4,4‘-H<sub>2</sub>bpy)[V<sub>2</sub>(HPO<sub>4</sub>)<sub>4</sub>(4,4‘-bpy)<sub>2</sub>], a Novel Two-Dimensional Network Compound

Ching-Hui Huang, Li‐Hsun Huang, Kwang‐Hwa Lii

Inorganic Chemistry · 2001 · 48 citations · 11 references

DOI

Concepts

Abstract

The synthesis and characterization of the first metal phosphate containing 4,4‘-bipyridine in two distinct forms is described; the structure consists of phosphate-bridged vanadium(III) chains, which are linked through 4,4‘-bipyridine ligands to form anionic {[V2(HPO4)4(4,4‘-bpy)2]2-}∞ sheets with the charge-compensating uncoordinated (4,4‘-H2bpy)2+ cations between the sheets.

References

11

Organic-Inorganic Hybrid Materials: From “Simple” Coordination Polymers to Organodiamine-Templated Molybdenum Oxides

Pamela J. Hagrman, Douglas Hagrman, Jon Zubieta · Angewandte Chemie International Edition · 1999 · 2.5K citations

, , +17

Open-Framework Inorganic Materials

Anthony K. Cheetham, Gérard Férey, Thierry Loiseau · Angewandte Chemie International Edition · 1999 · 2.4K citations

, , +15

Clathration of Two-Dimensional Coordination Polymers:  Synthesis and Structures of [M(4,4‘-bpy)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>·(2,4‘-bpy)<sub>2</sub>·H<sub>2</sub>O and [Cu(4,4‘-bpy)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>](ClO<sub>4</sub>)<sub>4</sub>·(4,4‘-H<sub>2</sub>Bpy) (M = Cd<sup>II</sup>, Zn<sup>II</sup> and bpy = Bipyridine)

Ming‐Liang Tong, Bao‐Hui Ye, Jiwen Cai et al. · Inorganic Chemistry · 1998 · 268 citations

, , +17

Hybrid Framework Iron(II) Phosphate-Oxalates

Amitava Choudhury, Srinivasan Natarajan, C. N. R. Rao · Journal of Solid State Chemistry · 1999 · 71 citations

, , +12

Hybrid Open-Framework Iron Phosphate-Oxalates Demonstrating a Dual Role of the Oxalate Unit

Amitava Choudhury, Srinivasan Natarajan, C. N. R. Rao · Chemistry - A European Journal · 2000 · 71 citations

, , +16