Publication | Closed Access
New catalytic route to borasiloxanes
28
Citations
19
References
2008
Year
Inorganic ChemistryChemical EngineeringEngineeringNew Catalytic RouteSelective MethodBoryl Silyl EthersOrganic ChemistryOrganometallic CatalysisCatalysisChemistrySynthesis MethodAsymmetric CatalysisSynthetic ChemistryCatalytic SynthesisEffective Synthesis
A new, highly selective method for effective synthesis of boryl silyl ethers (borasiloxanes) via O-borylation of silanols with vinylboronates catalyzed by the Ru-H complexes [RuHCl(CO)(PCy3)2] and [RuHCl(CO)(PPh3)3] is described.
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