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Stereo-controlled synthesis of erythronolides A and B from 1,6-anhydro-β-D-glucopyranose (levoglucosan). Skeleton assembly in (C9 – C13) + (C7 – C8) + (C1 – C6) sequence

BiosynthesisEngineeringBiochemistrySkeleton AssemblyErythronolides AGlycobiologyStereo-controlled SynthesisStereoselective SynthesisNatural Product SynthesisCarbohydrate-protein InteractionBiomolecular EngineeringGlycosylation