Concepedia

A three-dimensional ‘racemate’. Interpenetration of two enantiomeric networks of the SrSi<sub>2</sub>topological type in the polymeric complex [Ag<sub>2</sub>(2,3-Me<sub>2</sub>pyz)<sub>3</sub>][SbF<sub>6</sub>]<sub>2</sub>(2,3-Me<sub>2</sub>pyz = 2,3-dimethylpyrazine)

Lucia Carlucci, Gíanfranco Ciani, Davide Μ. Proserpio, Angelo Sironi

Chemical Communications · 1996 · 62 citations · 17 references

DOI

Concepts

Abstract

The polymeric species [Ag2(2,3-Me2pyz)3][SbF6]2 contains two three-dimensional three-connected cationic networks, belonging to the SrSi2 topological type, which are enantiomeric and interpenetrating, to give an unique case of a three-dimensional ‘racemate’.

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