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1,4 Addition of hexafluorobut-2-yne to co-ordinated cyclo-octa-1,5-diene: crystal structures of the adducts [Rh(acetylacetonato)(C<sub>8</sub>H<sub>12</sub>)(C<sub>4</sub>F<sub>6</sub>)(1½H<sub>2</sub>O)] and [Ir(acetylacetonato)(C<sub>8</sub>H<sub>12</sub>)(C<sub>4</sub>F<sub>6</sub>)<sub>2</sub>]
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1974
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Inorganic ChemistryCrystal StructureCo-ordinated Cyclo-octa-1,5-dieneEngineeringBiochemistryHeterocyclicNatural SciencesMolecular BiologyIridiacyclopentene Ring SystemStructure ElucidationOrganic ChemistryCrystal StructuresMolecular ComplexChemistryHeterocycle ChemistryHalogenationCrystallographyCrystal Structure Design
Hexafluorobut-2-yne adds 1,4 to co-ordinated cyclo-octa-1,5-diene in the complex [Rh(cod)Cl]2, in contrast to the reaction of hexafluorobut-2-yne with [Ir(acac)(cod)] which gives an iridiacyclopentene ring system.