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A Three‐Dimensional Framework of Novel Vanadium Clusters Bridged by [Ni(en)<sub>2</sub>]<sup>2+</sup>: Ni(en)<sub>3</sub>{V<sup>IV</sup><sub>11</sub>V<sup>V</sup><sub>5</sub>O<sub>38</sub> Cl [Ni (en)<sub>2</sub>]<sub>3</sub>}·8.5H<sub>2</sub>O
51
Citations
34
References
2003
Year
Materials ScienceInorganic ChemistryV 2Cluster ScienceEngineeringInorganic MaterialCovalent Bonded FrameworkCluster ChemistryCatalysisChemistryO 4H 2Three‐dimensional FrameworkFunctional MaterialsInorganic Synthesis
Abstract The hydrothermal reaction of V 2 O 5 , H 2 C 2 O 4 ·2H 2 O, KOH, en and NiCl 2 ·6H 2 O yields a new three‐dimensional open‐framework solid. The extended structure consists of a three‐dimensional network of [V 16 O 38 Cl] 8− cages, with each cage connected to six other neighboring units through [Ni(en) 2 ] 2+ bridging groups. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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