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Easy Procedures for the Synthesis of Soluble [2,3,9,10,16,17,23,24-Octakis(pentyloxy)phthalocyaninato]ruthenium(II) and (Phthalocyaninato)ruthenium(II)
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1992
Year
Inorganic ChemistryChemical EngineeringFirst SynthesisEngineeringCorresponding Metal-free PhthalocyanineCoordination ComplexEasy ProceduresBisquinoline Complex 9ChemistrySynthesis MethodSynthetic ChemistryInorganic SynthesisBiomolecular EngineeringInorganic Compound
The first synthesis of a pure, soluble substituted (phthalocyaninato)ruthenium(II), (C5H11O)8PcRu (4) by reaction of the corresponding metal-free phthalocyanine (C5H11O)8 PcH2 (3) with RuCl3 · xH2O in 2-ethoxyethanol is described. Also a new synthetic route for the unsubstituted (phthalocyaninato)ruthenium(II), PcRu (7) via the bisquinoline complex 9 is reported.