Canadian Journal of Chemistry · 1960 · 11 citations · 2 references
Natural SciencesChemistryPhysicsMolecular PhysicsOrganic ChemistryPhysical ChemistryChemical ReactionsChemical ThermodynamicsHydrogen AtomMolecular ThermodynamicsDeuteration ChemistryDeuterium ChemistryDeuterium Isotope EffectGas-phase ReactionsIsotopic Exchange ProcessesMelting
Measurements have been made of isotopic exchange and deuterium pressure change during deuterium atom bombardment of o-terphenyl, toluene, and eicosane just above their melting points. The number of molecules of HD formed was larger than the number of molecules lost or gained by the gas phase. A mechanism of reaction of deuterium atoms with aromatic liquids is proposed.
2
The Reaction of Atomic Hydrogen with Ethane
M. R. Berlie, D. J. LeRoy · The Journal of Chemical Physics · 1952 · 12 citations