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Ring-methyl activation in pentamethylcyclopentadienyliridium complexes; synthesis of [(C5Me4CH2E)IrL ] (E = SiMe3, PhCH2, CH2=CHCH2, PPh2, and Pt(PEt3)2Cl), and synthesis and X-ray structure of [(1,3-C5Me3(CH2SiMe3)2)Ir(CO)Me(Cl)]