Functionalized isocyanides as ligands. 4. Base-promoted cyclization reactions of free and platinum(II)-coordinated o-(phosphoniomethyl)phenyl isocyanide tetrafluoroborates, o-(BF4-R3PCH2)C6H4NC. Synthesis and spectroscopic characterization of 1- and 2-platinum(II)-substituted indole derivatives and x-ray structure of [cyclic] trans-.+-.[(PPh3)2Pt[CN(H)-o-C6H4C(PMe3)]Cl.+-.]Bf4.+-..C2H4Cl2 - Concepedia

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Functionalized isocyanides as ligands. 4. Base-promoted cyclization reactions of free and platinum(II)-coordinated o-(phosphoniomethyl)phenyl isocyanide tetrafluoroborates, o-(BF4-R3PCH2)C6H4NC. Synthesis and spectroscopic characterization of 1- and 2-platinum(II)-substituted indole derivatives and x-ray structure of [cyclic] trans-.+-.[(PPh3)2Pt[CN(H)-o-C6H4C(PMe3)]Cl.+-.]Bf4.+-..C2H4Cl2

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Citations

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References

1986

Year

Rino A. Michelin, Giacomo Facchin, Dario Braga, Piera Sabatino

Organometallics

Abstract

Base-promoted cyclization reactions of free and Platinum(II)-coordinated o-(phosphoniomethyl)phenyl isocyanide tetrafluoroborates, o-(BF4-R3P+-CH2)C6H4NC. Synthesis and spectroscopic characterization of 1-platinum(II)-substituted and 2-platinum(II)-substituted Indole-derivatives and X-ray Structure of Trans-((PPh3)2Pt[CN(H)-o-C6H4C(PMe3)]Cl)BF4.C2H4Cl2.