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A Convenient Procedure for Carboxylation—Robinson Annulations of Ketones Using Triethylamine Base in the Presence of Magnesium Chloride
15
Citations
6
References
1986
Year
Carbon DioxideNovel OrganocatalystsEngineeringMagnesium ChlorideCarboxylation—robinson AnnulationsCatalytic SynthesisOrganic ChemistryRobinson Annulation ProductsCatalysisStereoselective SynthesisChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringConvenient Procedure
Abstract Carboxylation of ketones with carbon dioxide in the presence of magnesium chloride and triethylamine followed by reaction with methyl vinyl ketone gives satisfactory yields of Michael and Robinson annulation products.
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