Acta Crystallographica Section C Crystal Structure Communications · 1994 · 22 citations · 0 references
Natural SciencesChemistryInorganic ChemistryOrganic ChemistryOrganometallic ChemistryCluster ChemistryCoordination ChemistryHeterocyclic ChemistryMetal-ligand BondingMolecular SymmetryTransition Metal ComplexesComplex OxidesCoordinationCoordination GeometryCoordination Geometry DeterminationImidazolylidene LigandsMetal-oxo Complexes
The title compound [Co 4 O(C 5 H 7 N 2 ) 6 ], consits of a central O atom coordinated by four Co II atoms which are themselves bridged in a pairwise fashion by six exobidentate 3,5-dimethylpyrazolate ligands. The coordination geometry about each Co I I atom is that of a distorted tetrahedron