‘Off–on’ fluorescent sensors for physiological levels of magnesium ions based on photoinduced electron transfer (PET), which also behave as photoionic OR logic gates

Abstract

The fluorescence of molecules 1–3 is enhanced by factors of up to 67 in the presence of magnesium and calcium ions in neutral water which allows the selective monitoring of magnesium ions under simulated physiological conditions and permits the construction of truth tables with OR logic when these molecules are viewed as ion input–photon output molecular devices.