Carrier antibiotics and model compounds as components of selective ion-sensitive electrodes

Abstract

ABSTRACT The ion selectivity exhibited by different types of membrane electrodes is rationalized by a theoretical treatment of the membrane potential. An equation, which is admirably suited for the interpolation of e.m.f.-values, is derived for the electrode response of membrane electrodes of the electrically neutral ligand type (antibiotics, model compounds) to mixed solutions of monovalent and divalent cations. In contrast to the classical Nicolsky equation it describes the contribution of interfering ions to the e.m.f. by an activity-independent selectivity term. Electrically neutral ligands selective for calcium ions to be used as components for liquid membrane electrodes were designed and prepared. The corresponding electrodes are in all respects superior to the calcium ion liquid membrane electrodes described so far.