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Kinetics of the thermal gas‐phase isomerization of 1,2‐epoxycyclohexane
15
Citations
15
References
1973
Year
Chemical EngineeringPrimary Reaction ProductsEngineeringThermal Gas‐phase IsomerizationOrganic ChemistryCatalysisThermodynamicsChemistryGas‐phase DecompositionMolecular KineticsChemical KineticsNonradical Processes
Abstract The kinetics of the gas‐phase decomposition of 1,2‐epoxycyclohexane has been studied over the temperature range 680–740 K at pressures between 1.6 and 6 torr. Isomerization to cyclohexanone and 2‐cyclohexen‐1‐ol accounts for ca. 97% of the primary reaction products and occurs by first‐order, homogeneous, nonradical processes:
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