Publication | Closed Access
<sup>13</sup>C NMR Determination of the Composition of Linear Low-Density Polyethylene Obtained with [η<sup>3</sup>-Methallyl-nickel-diimine]PF<sub>6</sub> Complex
445
Citations
15
References
1999
Year
Materials SciencePolymer MaterialEngineeringComplete 13CPolymer ScienceLinear Low-density PolyethyleneOrganic ChemistryNmr CharacterizationChemistryPolymer AnalysisNuclear Magnetic Resonance SpectroscopyMolecular PolymerPolymer ChemistryPolymer SynthesisLinear Low-density Polyethylenes
A complete 13C NMR characterization of two linear low-density polyethylenes (LLDPE), one highly branched and the other lowly branched, is presented. These LLDPE were synthesized with a new catalyst: the [η3-methallyl-nickel-dad]PF6 complex by homopolymerization of ethylene, using different experimental conditions. Methyl, ethyl, propyl, butyl, amyl, and long branches were assigned and quantified.
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