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A new tetradentate (N<sup>–</sup>)<sub>2</sub>S<sub>2</sub>macrocyclic ligand which is highly selective for platinum (<scp>II</scp>) and palladium (<scp>II</scp>)
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1989
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Inorganic ChemistryChemical EngineeringEngineeringCoordination ComplexNew TetradentateTetradentate Macrocyclic LigandOrganometallic CatalysisCatalysisComplex FormationChemistryMolecular ComplexHigh SelectivityInorganic SynthesisBiomolecular EngineeringInorganic Compound
A newly designed tetradentate macrocyclic ligand (H2L)(3), in which the two amide and two sulphide units act co-operatively, shows high selectivity and efficiency for complex formation with PtII and PdII over CuII, NiII, and CoII.