Publication | Closed Access
Generation and Reactions of Hypervalent Organic Selenium and Tellurium Compounds Having Aryl Ligands
21
Citations
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References
1992
Year
Inorganic ChemistryChemical EngineeringTetraaryl SelenuranesEngineeringInorganic SynthesisBiochemistryNatural SciencesHypervalent Organic SeleniumOrganic ChemistryOrganometallic CatalysisChemistryNmr StudiesHeterocycle ChemistryNatural Product SynthesisSynthetic ChemistryEnantioselective SynthesisLigand ExchangeInorganic Compound
Abstract The evidence for the formation of tetraaryl selenuranes as intermediates was presented in the ligand coupling reaction of triaryl-selenonium or diaryl selenoxide with phenyllithium (PhLi) by NMR studies. Triaryl telluranes were also formed as intermediates in the ligand exchange and disproportionation reactions of diaryl tellurides with PhLi.
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