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Efficient and Selective Hydroacylation of 1-Alkynes with Aldehydes by a Chelation-Assisted Catalytic System This work was supported by the National Research Laboratory Program (2000-N-NL-01-C-271) administered by the Ministry of Science and Technology.
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2002
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EngineeringOrganic ChemistryChemistryChemical Derivativeβ-Ungesättigten Ketonen UmsetzenChemical EngineeringNovel OrganocatalystsCorresponding AuthorCross-coupling ReactionBiochemistryCatalysisSiehe SchemaAsymmetric CatalysisEnantioselective SynthesisChelation-assisted Catalytic SystemSelective HydroacylationAlkene MetathesisNatural SciencesDerivative (Chemistry)
Terminale Alkine lassen sich in einer Chelat-unterstützten Hydroacylierung mit Aldehyden hervorragend zu verzweigten oder linearen Alkyl-substituierten α,β-ungesättigten Ketonen umsetzen (siehe Schema). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2002/z18824_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.