Die sterischen Bedingungen der Fragmentierungsreaktion III. Teil. Stereoisomere 4‐, 5‐ und 7‐Decahydrochinolyl‐toluolsulfonate Fragmentierungsreaktionen, 16. Mitteilung

Abstract

Abstract In a heterolytic fragmentation reaction of the type a‐b‐c‐d‐X → a ‐ b + c = d + : X the geometry of the d ‐ X bond and that of the electron‐donating group a relative to the b ‐ c bond are critical. This follows from a study of solvolysis rates and products of stereoisomeric 1‐methyl‐4‐, ‐5‐ and ‐7‐decahydroquinolyl p ‐toluenesulphonates in 80 Vol.% ethanol.