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Efficient and Stereodivergent Syntheses of <scp>D</scp>‐ and <scp>L</scp>‐Fagomines and Their Analogues
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Citations
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References
2008
Year
Their AnaloguesIntramolecular N‐heterocyclizationEngineeringBiochemistryNatural SciencesDiversity-oriented SynthesisSugar DerivativesD ‐GlycalsOrganic ChemistryStereodivergent SynthesesStereoselective SynthesisNatural Product SynthesisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract The syntheses of D ‐ and L ‐fagomines 1 , 4 , 5 and 6 and their isomers from starting D ‐glycals have been achieved. The syntheses involve elaboration of common amino alcohol precursors obtained from 2‐deoxy‐1‐amino sugar derivatives. The key steps in the syntheses are intramolecular reductive amination and intramolecular N‐heterocyclization. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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