Publication | Closed Access
A Versatile Synthesis of Annulated Carbazole Analogs Involving a Domino Reaction of Bromomethylindoles with Arenes/Heteroarenes
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Citations
71
References
2008
Year
DerivativesEngineeringArylated ProductsNatural SciencesDiversity-oriented SynthesisVersatile SynthesisOrganic ChemistryA Znbr 2Annulated Carbazole AnalogsChemistryDomino ReactionDiethylmalonate UnitHeterocycle ChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Abstract A ZnBr 2 ‐mediated arylation of aryl/heteroaryl methyl bromides with arenes at 80 °C led to the formation of arylated products, which underwent subsequent 1,5‐sigmatropic rearrangement followed by electrocyclization and aromatization with loss of a diethylmalonate unit to afford the corresponding annulated products. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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