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Synthesis of 1,1-Disubstituted Ethenes by Means of Sequential Cross-Coupling Reactions
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1987
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Chemical EngineeringCross-coupling ReactionEngineeringAlkene MetathesisTransition-metal CatalystsGrignard ReagentsOrganic ChemistryOrganometallic CatalysisCatalysisChemistrySequential Cross-coupling ReactionsEnantioselective Synthesis
A variety of 1-alkenes are synthesized in 63-91% yields by means of sequential cross-coupling reactions of Grignard reagents with readily available or commercial starting materials, in the presence of transition-metal catalysts.