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Solvothermal Synthesis, Crystal Structure, Thermal Stability, and Mössbauer Spectroscopic Investigation of the Mixed-Valent Thioantimonate(III,V) [Ni(dien)2]2Sb4S9
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2002
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Materials ScienceInorganic ChemistrySb3s7 BackboneContains Sbvs4 TetrahedraEngineeringCrystal StructureBiochemistryNatural SciencesSolvothermal SynthesisMain Group ChemistryChemistryInorganic MaterialCrystallographyInorganic SynthesisThermal StabilityOxidation StatesInorganic Compound
Antimony in two oxidation states: The mixed-valent thioantimonate anion [Sb4S9]4− in the compound [Ni(dien)2]2Sb4S9 contains SbVS4 tetrahedra, which are bound by one terminal S atom to the Sb3S7 backbone of the anion (see figure). dien=diethylenetriamine.