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9-Fluorenylmethyl Pentafluorophenyl Carbonate as a Useful Reagent for the Preparation of<i>N</i>-9-Fluorenylmethyloxycarbonylamino Acids and their Pentafluorophenyl Esters
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1986
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New CompoundsEngineeringAmino AcidsBiochemistryNatural SciencesFluorous SynthesisOrganic ChemistrySynthetic ChemistryChemistryPentafluorophenyl EstersDerivative (Chemistry)Useful ReagentBiomolecular EngineeringPentafluorophenyl Carbonate
9-Fluorenylmethyl pentafluorophenyl carbonate is a useful reagent for the efficient, side reaction-free introduction of N-9-fluorenylmethyloxycarbonyl protecting group into amino acids and for the subsequent preparation of their pentafluorophenyl esters. Some new compounds of both types are described.