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Tricritical Exponents for the Isotropic-nematic Transition: An Experimental Verification
82
Citations
8
References
1979
Year
EngineeringMagnetic ResonanceMean-field TheoryStatistical Field TheoryMagnetismQuantum MaterialsTricritical ExponentsPhysicsGap ExponentInduced BirefringenceQuantum ChemistryQuantum MagnetismMicrowave SpectroscopyPhase EquilibriumNatural SciencesApplied PhysicsCondensed Matter PhysicsMagnetic PropertyMagnetic FieldChemical Kinetics
The gap exponent for the isotropic-nematic phase transition in MBBA (N-[$p$-methoxybenzylidine]-$p$-butylaniline) has been determined from measurements of the induced birefringence in very strong magnetic fields. The experimental value, $\ensuremath{\Delta}=1.26\ifmmode\pm\else\textpm\fi{}0.10$, is consistent with the tricritical exponent, $\ensuremath{\Delta}=\frac{5}{4}$, but is clearly inconsistent with the exponent $\ensuremath{\Delta}=2$ predicted by the mean-field theory. It is also shown that some of the observed effects are more than two orders of magnitude larger than the values predicted by the mean-field theory.
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