Surface Design in Solid‐State Dye Sensitized Solar Cells: Effects of Zwitterionic Co‐adsorbents on Photovoltaic Performance

TLDR

In solid‑state dye‑sensitized solar cells, charge recombination at the dye–hole transporting material interface critically limits efficiency. This study reports, for the first time, how dipolar co‑adsorbents influence photovoltaic performance in sensitized heterojunction solar cells. The authors examined two zwitterionic butyric acid derivatives (GBA and ABA) as co‑adsorbents with Z907Na dye on SSDSCs, using impedance and transient photovoltage measurements to probe their impact. The Z907Na/GBA combination raised both Voc and Jsc relative to dye alone, while the Z907Na/ABA combination increased only Jsc.

Abstract

Abstract In solid‐state dye sensitized solar cells (SSDSCs) charge recombination at the dye‐hole transporting material interface plays a critical role in the cell efficiency. For the first time we report on the influence of dipolar co‐adsorbents on the photovoltaic performance of sensitized hetero‐junction solar cells. In the present study, we investigated the effect of two zwitterionic butyric acid derivatives differing only in the polar moiety attached to their common 4 carbon‐chain acid, i.e., 4‐guanidinobutyric acid (GBA) and 4‐aminobutyric acid (ABA). These two molecules were implemented as co‐adsorbents in conjunction with Z907Na dye on the SSDSC. It was found that a Z907Na/GBA dye/co‐adsorbent combination increases both the open circuit voltage ( V oc ) and short‐circuit current density ( J sc ) as compared to using Z907Na dye alone. The Z907Na/ABA dye/co‐adsorbent combination increases the J sc . Impedance and transient photovoltage investigations elucidate the cause of these remarkable observations.