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Charge Transport versus Optical Properties in Semiconducting Crystalline Organic Thin Films
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2000
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Optical MaterialsEngineeringOrganic ElectronicsChemistryPolymersOptical PropertiesPrototypical Oligomeric MaterialsCharge Carrier TransportPolymer ChemistryOrganic SemiconductorPhysical ChemistryPolymer Thin FilmsOrganic Charge-transfer CompoundElectronic MaterialsSemiconducting PolymerPolymer ScienceApplied PhysicsOrganic OligomerThin Films
A theoretical approach to the characterization of the transport and optical properties of organic oligomer and polymer thin films is proposed. The approach—based on a correlated treatment of interchain interactions—is applied to two prototypical oligomeric materials, α-sexithienyl and α-α′-bisdithieno- [3,2-b:2′,3′-d]thiophene (see Figure).