Publication | Closed Access
Isomerization and dealkylation reactions of nickel(<scp>II</scp>) complexes of macrocyclic tertiary amine ligands: X-ray crystal structures of {Ni[1,4,8,11-tetra(2-cyanoethyl)-1,4,8,11-tetra-azacyclotetradecane](NCMe)<sub>2</sub>}(ClO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O and {Ni[1,8-di (2-carbamoylethyl)-4-(2-cyanoethyl)-1,4,8,11-tetra-azacyclotetradecane]}(ClO<sub>4</sub>)<sub>2</sub>
13
Citations
0
References
1983
Year
Inorganic CompoundInorganic ChemistryChemical EngineeringEngineeringNitrogen Inversion ReactionsNitrogen SubstituentsCoordination ComplexOrganic ChemistryOrganometallic CatalysisMolecular ComplexChemistryX-ray Crystal StructuresCyanoethyl SubstituentInorganic SynthesisBiomolecular EngineeringDealkylation Reactions
Nitrogen inversion reactions have been observed in nickel(II) complexes of macrocyclic tertiary tetra-amine ligands in which the nitrogen substituents are either 2-cyanoethyl or 2-carbamoylethyl; under certain conditions dealkylative loss of the cyanoethyl substituent occurs but loss of a carbamoyl substituent has not been observed for nickel(II) although it has for copper(II).