Concepedia

A NEW SYNTHETIC METHOD FOR 1-METHOXY-2-ALKANONES FROM 1,2-DIMETHOXYETHENYLLITHIUM AND ORGANOBORANES

J. KOSHINO, Takahiro Sugawara, Toshinobu Yogo, Akira Suzuki

Chemistry Letters · 1983 · 10 citations · 2 references

DOI

Concepts

Abstract

Abstract 1-Methoxy-2-alkanones are prepared from ate-complexes formed from 1,2-dimethoxyethenyllithium and trialkylboranes by the reaction with BF3:Et2O, followed by basic hydrogen peroxide oxidation.

References

2

1,2-Dimethoxyvinyllithium–A Useful New Reagent

Carl N. Skold · Synthetic Communications · 1976 · 27 citations

, , +8

The synthesis of methoxycyclopropanes via the treatment of ate-complexes obtained from B-alkyl-9-borabicyclo[3,3,1]nonanes and lithium methoxyallene with acetic acid

Norio Miyaura, Tomohiro Yoshinari, Mitsuomi Itoh et al. · Tetrahedron Letters · 1980 · 18 citations

, , +12