Combination of crystal-field dependent and independent paramagnetic NMR hyperfine shift analysis methods for investigating the solution structures of inert self-assembled heterodimetallic d–f supramolecular complexes †

Abstract

Tables of molecular peaks obtained by ESI-MS, longitudinal and transverse relaxation times, axial paramagnetic anisotropies and axial co-ordinates for (HHH)-[LnCo IIIL 3] 6+ in acetonitrile; tables of least-squares planes and structural data for 6 and 7; tables of geometric factors R ik and intercepts F″ i − F kR ik for (HHH)-[LnCo II(L) 3] 5+ in acetonitrile; figures showing packing in 7, linear plots of relaxation rates versus the square of magnetic fields for (HHH)-[LnCo IIL 3] 6+ and a plot of Δ ij/<S z> j vs. Δ kj/<S z> j for H 12–H 13 in (HHH)-[LnCo IIL 3] 5+ in acetonitrile DOC (512K) Crystal structure data TXT (69K)