Carbon nanotubes for gas detection: materials preparation and device assembly

Abstract

An efficient sensing device for NH3 and NOx detection has been realized using ordered arrays of single-walled C nanotubes deposited onto an interdigitated electrode platform operating at room temperature. The sensing material has been prepared using several chemical–physical techniques for purification and positioning of the nanotubes inside the electrode gaps. In particular, both DC and AC fields have been applied in order to move and to align the nanostructures by electrophoresis and dielectrophoresis processes. We investigated the effects of different voltages applied to a gate contact on the back side of the substrate on the performances of the device and found that for different gas species (NH3, NOx) a constant gate bias increases the sensitivity for gas detection. Moreover, in this paper we demonstrate that a pulsed bias applied to the gate contact facilitates the gas interaction with the nanotubes, either reducing the absorption times or accelerating the desorption times, thus providing a fast acceleration and a dramatic improvement of the time dependent behaviour of the device.