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Exact Solution for an<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>N</mml:mi></mml:math>-Molecule—Radiation-Field Hamiltonian
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7
References
1968
Year
Identical Two-level MoleculesLocalized Excited StateEngineeringComputational ChemistryElectronic Excited StateMath XmlnsExcited StatesBiophysicsQuantum SciencePhysicsDipole CouplingAtomic PhysicsRadiation TransportQuantum ChemistryExcited State PropertyNatural SciencesDouble ResonanceHamiltonian SystemMany-body Problem
The exact solution for a problem of $N$ identical two-level molecules interacting through a dipole coupling with a single-mode quantized radiation field at resonance is given. Approximate expressions for the eigenvectors and eigenvalues for the ground and low-lying excited states, as well as the most highly excited states, are developed and compared with the exact results.
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