Publication | Closed Access
Synthesis and Characterization of New Binuclear Co(0) Complexes with Diphosphinoamine Ligands. A Potential Approach for Asymmetric Pauson−Khand Reactions
56
Citations
21
References
1999
Year
Inorganic ChemistryChemical EngineeringPauson-khand ReactionDiphosphinoamine LigandsNew Binuclear CoEngineeringCoordination ComplexP-n-p Bidentate LigandsOrganic ChemistryOrganometallic CatalysisMolecular ComplexPi-acceptor PropertiesChemistryAsymmetric Pauson−khand ReactionsInorganic SynthesisBiomolecular EngineeringInorganic Compound
The synthesis of P-N-P bidentate ligands and the evaluation, based on IR and X-ray data, of their pi-acceptor properties in the complexes derived from phenylacetylene-dicobalt hexacarbonyl have been carried out. In addition, the reactivity of these complexes in the Pauson-Khand reaction has been examined.
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