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Dianions and Tetraanions of Bowl-Shaped Fullerene Fragments Dibenzo[a,g]corannulene and Dibenzo[a,g]cyclopenta[kl]corannulene
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1998
Year
Materials ScienceFullerene Fragment 1Organic Material ChemistryC60 NetworkEngineeringHeterocyclicFullereneOrganic ChemistryPhysical ChemistryMain Group ChemistryChemistryAlkali Metal ReductionLinear Chain Compound
The fullerene fragment 1 (C28H14) gives a paratropic dianion and a diatropic tetraanion on alkali metal reduction, whereas the C30H14 hydrocarbon 2, which contains just one more ring from the C60 network, gives a diatropic dianion and a paratropic tetraanion.