Hydrogenation and isomerisation of alkenes using IrCl(PPh3)2 and the isolation of the oxygen adduct IrCl(PPh3)2(O2)-(C2H4),C6H6. - Concepedia

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Hydrogenation and isomerisation of alkenes using IrCl(PPh3)2 and the isolation of the oxygen adduct IrCl(PPh3)2(O2)-(C2H4),C6H6.

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References

1970

Year

H. van Gaal, H. G. A. M. Cuppers, Antony van der Ent

Journal of the Chemical Society D Chemical Communications

Chemical EngineeringEngineeringHeterocyclicAlkene MetathesisFive-co-ordinated Adduct IrclOrganic ChemistryOrganometallic CatalysisCatalysisHydrogenChemistryMolecular Oxygen IrclOxygen Adduct Ircl

Abstract

IrCl(PPh3)2, prepared in situ, has been found to be a catalyst for the hydrogenation and isomerisation of alkenes; with molecular oxygen IrCl(PPh3)2(C2H4) forms in benzene the five-co-ordinated adduct IrCl(PPh3)2(O2)(C2H4),C6H6.