Non-steady-state measurements of the thermal conductivities of liquid polyphenyls

Abstract

Abstract A line source technique has been developed for non-steady-state measurements of the therm al conductivities of liquids over an extended range of temperature. The accuracy of the method, which is an absolute one, has been critically exam ined. T hermal conductivities of liquid benzene, toluene, diphenyl, o-,m - and^p-terphenyl, estimated to be accurate to + 0*25 % , have been obtained. These results are discussed in terms of the effect of structure on the transport properties of liquids and the relation between the coefficient of thermal expansion and the temperature dependence of thermal conductivity.