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Tuning of reactivity in epoxidation of alkenes by iron and ruthenium complexes associated to non-porphyrinic ligands
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1985
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Inorganic ChemistryChemical EngineeringEngineeringCoordination ComplexRuthenium ComplexesOrganic ChemistryOrganometallic CatalysisCatalysisRedox ChemistryChemistryNon-porphyrinic LigandsMolecular ComplexInorganic SynthesisElectron DonatingInorganic Compound
RuCl3·n(H2O) or FeSO4 associated with bipyridyl or substituted phenanthrolines, catalyse the expoxidation of stilbenes by IO4– or ClO–; using phenanthrolines bearing electron donating or withdrawing groups, it is possible to modulate the reactivity of these systems.