Reactivity of scandium terminal imido complexes towards metal halides

Abstract

Reactions of scandium terminal imido complexes with CuI and [M(COD)Cl](2) (M = Rh, Ir) show two interesting reaction patterns, and the formed heterobimetallic complexes have intriguing structural features and show promising catalytic properties.

References

Page 1

	Year	Citations
Covalent radii revisited Beatriz Cordero, Verónica Gómez, Ana E. Platero‐Prats, Dalton Transactions Crystal StructureEngineeringPhysicsNatural SciencesChemical Bond	2008	4K
Living ring-opening metathesis polymerization catalyzed by well-characterized transition-metal alkylidene complexes Richard R. Schrock Accounts of Chemical Research Inorganic ChemistryChemical EngineeringEngineeringAlkene MetathesisDonut Icon	1990	816
Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2 Patrick J. Walsh, Anne M. Baranger, Robert G. Bergman Journal of the American Chemical Society Materials ScienceChemical EngineeringEngineeringZirconium Bisamides Cp2zrAltmetric Attention Score	1992	426
Addition of Metalloid Hydrides to Alkynes: Hydrometallation with Boron, Silicon, and Tin Barry M. Trost, Zachary T. Ball Synthesis Materials ScienceInorganic ChemistryAsymmetric CatalysisBoron NitrideEngineering	2005	396
Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes Patrick J. Walsh, Frederick J. Hollander, Robert G. Bergman Journal of the American Chemical Society Alkyne CycloadditionInorganic ChemistryNitrogen-hydrogen ActivationEngineeringBiochemistry	1988	383
Methane and benzene activation via transient (tert-Bu3SiNH)2Zr:NSi-tert-Bu3 Christopher C. Cummins, Steven M. Baxter, Peter T. Wolczanski Journal of the American Chemical Society Molecular SciencesEngineeringChemical MeasurementChemical AnalysisNatural Sciences	1988	354
Olefin metathesis by molybdenum imido alkylidene catalysts Richard R. Schrock Tetrahedron Alkene MetathesisCatalysisChemistryCatalytic SynthesisOlefin Metathesis	1999	282
Reactions and Applications of Titanium Imido Complexes Nilay Hazari, Philip Mountford Accounts of Chemical Research Materials ScienceInorganic ChemistryEngineeringTitanium Imido ComplexesCoordination Complex	2005	277
Oxidatively Induced Abstraction Reactions. A Synthetic Approach to Low-Coordinate and Reactive Early Transition Metal Complexes Containing Metal−Ligand Multiple Bonds Daniel J. Mindiola Accounts of Chemical Research	2006	271
Design and Magnetic Properties of a Magnetically Isolated Gd<sup>III</sup>Cu<sup>II</sup> Pair. Crystal Structures of [Gd(hfa)<sub>3</sub>Cu(salen)], [Y(hfa)<sub>3</sub>Cu(salen)], [Gd(hfa)<sub>3</sub>Cu(salen)(Meim)], and [La(hfa)<sub>3</sub>(H<sub>2</sub>O)Cu(salen)] [hfa = Hexafluoroacetylacetonato, salen = <i>N</i>,<i>N</i>‘-Ethylenebis(salicylideneaminato), Meim = 1-Methylimidazole] Isabelle Ramade, Olivier Kahn, Yves Jeannin, Inorganic Chemistry	1997	265

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