Regioselective trifluoromethylation of N-heteroaromatic compounds using trifluoromethyldifluoroborane activator

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

David A. Nagib, David W. C. MacMillan · Nature · 2011 · 1.3K citations · Full text

Natural Sciences, Chemical Engineering, Chemistry +12

Practical and innate carbon–hydrogen functionalization of heterocycles

Yuta Fujiwara, Janice A. Dixon, Fionn O’Hara et al. · Nature · 2012 · 924 citations · Full text

Natural Sciences, Chemistry, Medicinal Chemistry +12

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

Eun Jin Cho, Todd D. Senecal, Tom Kinzel et al. · Science · 2010 · 779 citations

Pharmacy, Chemistry, Medicinal Chemistry +10

Innate C-H trifluoromethylation of heterocycles

Yining Ji, Tobias Brueckl, Ryan D. Baxter et al. · Proceedings of the National Academy of Sciences · 2011 · 755 citations

Natural Sciences, Chemistry, Medicinal Chemistry +12

Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF₃I

Yingda Ye, Melanie S. Sanford · Journal of the American Chemical Society · 2012 · 677 citations · Full text

Natural Sciences, Chemistry, Catalysis +15