Concepedia

Azidohydroperoxidation of pinenes: stereoselectivity pattern and the first X-ray structure of a 2-azidohydroperoxide

Axel G. Griesbeck, Johann Lex, Kurt M. Saygin, Jörg Steinwascher

Chemical Communications · 2000 · 18 citations · 10 references

DOI

Concepts

Abstract

The photoinduced electron transfer of azide anions in the presence of an excited organic dyestuff, oxygen, and α- or β-pinene, respectively, gave 2-azidohydroperoxides in excellent regio- and good diastereoselectivity.

References

10

Rate constants for the reactions of free radicals with oxygen in solution

B. Maillard, K. U. Ingold, J. C. Scaiano · Journal of the American Chemical Society · 1983 · 496 citations

, , +12

Azidyl Radical Reactivity. N6.bul.- as a Kinetic Probe for the Addition Reactions of Azidyl Radicals with Olefins

Mark S. Workentin, Brian D. Wagner, Janusz Lusztyk et al. · Journal of the American Chemical Society · 1995 · 65 citations

, , +11

A practical method for preparation of optically pure oxazaborolidines from α-Pinene

Moriyasu Masui, Takayuki Shioiri · Tetrahedron · 1995 · 49 citations

, , +5

N6.bul.-. Spectroscopic and Theoretical Studies of an Unusual Pseudohalogen Radical Anion

Mark S. Workentin, Brian D. Wagner, Fabrizia Negri et al. · The Journal of Physical Chemistry · 1995 · 48 citations

, , +7

Mechanism of the Reaction of <sup>1</sup>δ<sub>g</sub> Excited Oxygen with Olefins. II. Elimination of the Concerted "Ene" Mechanism as the Route to Allylic Hydroperoxides

William Fenical, David R. Kearns, Phillip Radlick · Journal of the American Chemical Society · 1969 · 44 citations

, , +6