Concepedia

Coordinatively Unsaturated Transition Metal‐Substituted Cyclopropenylium Systems

Claus Priesner

Angewandte Chemie International Edition in English · 1978 · 30 citations · 7 references

DOI

Concepts

Abstract

A 14-electron system and hence possibly a novel catalyst has been found in the Pd-substituted, coordinatively unsaturated cyclopropenylium salt (1) (and its CF3SO analog). 14-electron systems play an important role in homogeneous catalysis.

References

7

The first formally three-coordinate d8 complex: tris(triphenylphosphine)rhodium(I) perchlorate and its novel structure

Yohannes W. Yared, Susan L. Miles, Robert Bau et al. · Journal of the American Chemical Society · 1977 · 120 citations

, , +13

Dichlor(2,3-diphenylcyclopropenyliden)palladium(II)

Karl Öfele · Journal of Organometallic Chemistry · 1970 · 49 citations

σ‐Dicarbonylcyclopentadienyliron Derivatives of Cyclopropenes and Cyclopropenylium Salts

R. Gompper, Ekkehard Bartmann · Angewandte Chemie International Edition in English · 1978 · 44 citations

, , +10

S<sub>E</sub> Reactions on the C‐Ring: σ‐Attack

Claus Priesner, Hilmar Wolf · Angewandte Chemie International Edition in English · 1978 · 44 citations

Toward metallocyclopropenium ions: redox cleavage of diorganyldichalcogenides by trichlorocyclopropenium salts

C. Schlierf, Klaus Schloter · Journal of the American Chemical Society · 1976 · 39 citations

, , +11