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First total syntheses and absolute configuration of rugulactone and 6(R)-(4′-oxopent-2′-enyl)-5,6-dihydro-2H-pyran-2-one

Bioorganic ChemistryBiochemistryNatural SciencesDiversity-oriented SynthesisOrganic ChemistryFirst Total SynthesesChemistrySynthetic ChemistryEnantioselective Synthesis