White-light electroluminescence from soluble oxadiazole-containing phenylene vinylene ether-linkage copolymer

Abstract

We report a promising oxadiazole-containing phenylene vinylene ether-linkage copolymer, which can emit nearly white light from a single-layer light-emitting diode. The emission spectrum is composed of a red component originating from the new excited dimer in addition to the blue-green component from an individual lumophore and excimer. This excited dimer is formed under a strong electric field inside the diode and cannot be produced by photoexcitation, which is different from the excimer or exciplex that is often found both in photoluminescence and electroluminescence, and it is termed the “electromer.”