Concepedia

Copper(I) Chelate Complexes with Novel <i>π</i>-Conjugated 1,2-Bis(2-pyridylethynyl)benzene Ligands: Synthesis, Structure, and Reactivity

Tomikazu Kawano, Jun Kuwana, Tatsuji Shinomaru, Chong‐Xu Du, I. Ueda

Chemistry Letters · 2001 · 27 citations · 6 references

DOI

Concepts

Abstract

Abstract Novel π-conjugated nitrogen ligands, 1,2-bis(2-pyridylethynyl)benzenes, and their Cu(I) complexes have been synthesized and structurally characterized: the reactivity of the complexes for radical cyclization has also been examined.

References

6

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Copper—A “Modern” Bioelement

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William B. Tolman · Accounts of Chemical Research · 1997 · 479 citations

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A New Class of Planar−Chiral Ligands:  Synthesis of a <i>C</i><sub>2</sub>-Symmetric Bisazaferrocene and Its Application in the Enantioselective Cu(I)-Catalyzed Cyclopropanation of Olefins

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Transition metal-catalyzed radical cyclizations: a low-temperature process for the cyclization of N-protected N-allyltrichloroacetamides to trichlorinated .gamma.-lactams and application to the stereoselective preparation of .beta.,.gamma.-disubstituted .gamma.-lactams

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