Concepedia

Rapid hydroformylation of alkyl acrylates in supercritical CO2

Yulai Hu, Weiping Chen, Anna M. Banet Osuna, Jianliang Xiao, Alison M. Stuart, Eric G. Hope

Chemical Communications · 2001 · 39 citations · 10 references

DOI

Concepts

Abstract

Fast and regioselective hydroformylation of alkyl acrylates can readily be accomplished in supercritical CO2 (scCO2), which promotes the reaction probably via specific solvent–solute interactions.

References

10

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Rhodium-Catalyzed Hydroformylation in Supercritical Carbon Dioxide

Daniel Koch, Walter Leitner · Journal of the American Chemical Society · 1998 · 267 citations

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Zwitterionic rhodium complexes as catalysts for the hydroformylation of olefins

Ibrahim Amer, Howard Alper · Journal of the American Chemical Society · 1990 · 95 citations

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Enhancement of Catalytic Activity for Hydroformylation of Methyl Acrylate by Using Biphasic and “Supported Aqueous Phase” Systems

Georges Frémy, Éric Monflier, Jean‐François Carpentier et al. · Angewandte Chemie International Edition in English · 1995 · 89 citations

, , +11

A new, highly selective, water-soluble rhodium catalyst for methyl acrylate hydroformylation

Georges Frémy, Yves Castanet, Ryszard Grzybek et al. · Journal of Organometallic Chemistry · 1995 · 61 citations

, , +8