Family of High-Temperature Polymer-Electrolyte Membranes Synthesized from Amphiphilic Nanostructured Macromolecules

Abstract

A family of amphiphilic organic/inorganic hybrid electrolyte membranes has been synthesized through sol-gel processing of bridged polysilsesquioxane macromolecules. The membrane doped with acidic moieties such as 12-phosphotungstic acid (PWA), shows proton conductivities larger than at temperatures up to 160°C. An effect of the nanostructure of the amphiphilic hybrid macromolecules on proton conductivity is discussed. The proton conducting properties of the bridged alkylene hybrid membranes with various organic bridging groups were investigated in the range of 100 to 160°C and at a relative humidity from 20 to 100%. The octane hybrid membrane showed a conductivity of approximately up to 160°C and a temperature stability up to 400°C. A stable conductivity above 100°C, which is relatively insensitive to the humidity level, suggests a robust conductive channel structure in the flexible macromolecules. The organic/inorganic hybrids synthesized from amphiphilic polysilsesquioxane families show promise for applications in intermediate temperature polymer electrolyte fuel cells. © 2003 The Electrochemical Society. All rights reserved.