Total synthesis of malyngamide M and isomalyngamide M

A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)

E. J. Corey, P.L. Fuchs · Tetrahedron Letters · 1972 · 1.6K citations

Natural Sciences, Chemical Engineering, Chemistry +7

Bis(((<i>S</i>)-binaphthoxy)(isopropoxy)titanium) Oxide as a μ-Oxo-Type Chiral Lewis Acid:  Application to Catalytic Asymmetric Allylation of Aldehydes

Hideo Hanawa, Takuya Hashimoto, Keiji Maruoka · Journal of the American Chemical Society · 2003 · 190 citations

Natural Sciences, Chemistry, Catalysis +12

Expedient Synthesis of Chiral 1,2- and 1,4-Diamines:  Protecting Group Dependent Regioselectivity in Direct Organocatalytic Asymmetric Mannich Reactions

Naidu S. Chowdari, Moballigh Ahmad, Klaus Albertshofer et al. · Organic Letters · 2006 · 125 citations

Natural Sciences, Chemistry, Medicinal Chemistry +11

Efficient Synthetic Access to the Hetisine C₂₀-Diterpenoid Alkaloids. A Concise Synthesis of Nominine via Oxidoisoquinolinium-1,3-Dipolar and Dienamine-Diels−Alder Cycloadditions

Kevin M. Peese, David Y. Gin · Journal of the American Chemical Society · 2006 · 118 citations · Full text

Natural Sciences, Chemistry, Medicinal Chemistry +11

Asymmetric transfer hydrogenation of α,β-unsaturated, α-tosyloxy and α-substituted ketones

Philip Peach, David J. Cross, Jennifer A. Kenny et al. · Tetrahedron · 2005 · 104 citations

Natural Sciences, Chemistry, Reaction Engineering +7