Publication | Closed Access
Chemical Applications of NMR Isotope Effects: Ring Inversion and Conformational Equilibrium in [<sup>2</sup>H<sub>1</sub>]Cyclohexane
19
Citations
13
References
1981
Year
Nmr Isotope EffectsChemical ApplicationsEngineeringNuclear PhysicsMagnetic ResonanceChemical ShiftOrganic ChemistryRing InversionChemistryNuclear Quadrupole ResonanceHigh-energy Nuclear ReactionBiochemistryPhysicsIsotope EffectConformational EquilibriumExperimental Nuclear PhysicsNatural SciencesIsotope GeochemistryRadioanalytical ChemistryNuclear Magnetic Resonance Spectroscopy
The large and easily measurable 1H/2H isotope effect on the chemical shift of the 13C nucleus has been exploited in the investigation of the ring inversion (1a)⇌(1b). At equilibrium, (1a) predominates.
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